这里有段VB6.0的，你可以参考。
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注意添加引用。
Private Sub Command6_Click()
Dim i, j As Integer
Dim xlApplication As Excel.Application, xlWorkbook As Excel.Workbook, xlSheet
Dim xlApp As Excel.Application
On Error Resume Next
Set xlApplication = GetObject(, "Excel.Application")
Set xlApp = CreateObject("Excel.Application")
If MsgBox("确认将文件信息导出到EXCEL中？�", vbExclamation + vbYesNo, "警告") = vbYes Then
If Err.Number 0 Then Set xlApplication = CreateObject("Excel.Application")
Set xlWorkbook = xlApplication.Workbooks.Add
Set xlSheet = xlWorkbook.ActiveSheet
xlSheet.Cells(1, 2) = lblcl.Caption
xlSheet.Range("A1:E1").MergeCells = True
xlSheet.Range("A1:E1").HorizontalAlignment = xlCenter
xlSheet.Cells(2, 2).ColumnWidth = 18
For i = 1 To DataGrid1.Columns.Count
xlSheet.Cells(2, 1) = "编号"
xlSheet.Cells(2, i + 1) = DataGrid1.Columns(i).Caption
For j = 0 To DataGrid1.VisibleRows - 1
xlSheet.Cells(j + 3, 1) = j + 1
xlSheet.Cells(j + 3, i + 1) = DataGrid1.Columns(i).CellText(DataGrid1.RowBookmark(j))
Next j
Next i
xlApplication.Visible = True
Set xlSheet = Nothing
Set xlWorkbook = Nothing
Set xlApplication = Nothing
'xlApp.Range("A2:L2").Columns.Interior.ColorIndex = 40
'xlApp.Range("A2:L2").Borders.LineStyle = xlContinuous
'xlApp.Visible = True
'xlApp.Range(xlSheet.Cells(2 + PartsRs.RecordCount + 1, 1), xlSheet.Cells(2 + PartsRs.RecordCount + 1, 8)).Columns.Interior.ColorIndex = 40
'xlApp.Range(xlSheet.Cells(2 + PartsRs.RecordCount + 1, 1), xlSheet.Cells(2 + PartsRs.RecordCount + 1, 8)).Borders.LineStyle = xlContinuous
Else
MsgBox "无信息可供您导出，请确认!", vbExclamation + vbOKOnly, "警告"
End If
End Sub
不好意思 现在才看到；Private Sub 导出EXCEL_Click(ByVal sender As System.Object, ByVal e As System.EventArgs) Handles Button3.Click
Dim xlApp, xlBook, xlSheet As Object
xlapp = CreateObject("Excel.Application")
xlbook = xlapp.Workbooks.Add
xlsheet = xlbook.Worksheets(1)
'Dim xlapp As New Excel.Application
'Dim xlbook As Excel.Workbook
'Dim xlsheet As Excel.Worksheet
Dim rowindex, colindex As Integer rowindex = 1 '行
colindex = 0 '列
'xlbook = xlapp.Workbooks.Open("c:\EXCEL.xls") '打开EXCEL文件
xlsheet = xlapp.Worksheets("sheet1") '打开sheet1那页 Dim a As New DataSet
Dim table As New System.Data.DataTable table = DataSet11.Tables("INVMATLISTA") '填充表 Dim row As DataRow '定义row为表格的行
Dim col As DataColumn '定义col为表格的列 '把表格的每一列写到EXCEL去
For Each col In table.Columns
colindex = colindex + 1
xlapp.Cells(1, colindex) = col.ColumnName Next
'把表格的每一行写到EXCEL去
For Each row In table.Rows
rowindex = rowindex + 1
colindex = 0
For Each col In table.Columns
colindex = colindex + 1
xlapp.Cells(rowindex, colindex) = row(col.ColumnName)
Next
Next
xlapp.Visible = True
End Sub 前提要先引用一个Microsoft.Office.Interop.Excel.dll然后在最上面先输入Imports Microsoft.Office.Interop； 就可以了
介绍
下面通过一步一步的介绍，如何通过VB.NET来读取数据，并且将数据导入到Excel中。
第一步：
打开VS开发工具，并且添加引用。
然后选择。
Microsoft Excel 12.0 object library and。
Microsoft Excel 14.0 object library。
第二步：
创建一个Excle在你的电脑中。
第三步：
在VS中写入如下代码：
Imports System.Data
Imports System.Data.SqlClient
Imports Excel = Microsoft.Office.Interop.Excel。
Public Class excel
‘添加按钮
Private Sub Button1_Click(ByVal sender As System.Object, ByVal e As System.EventArgs) _
Handles Button1.Click
Try
'创建连接
Dim cnn As DataAccess = New DataAccess(CONNECTION_STRING)
Dim i, j As Integer
'创建Excel对象
Dim xlApp As Microsoft.Office.Interop.Excel.Application
Dim xlWorkBook As Microsoft.Office.Interop.Excel.Workbook
Dim xlWorkSheet As Microsoft.Office.Interop.Excel.Worksheet
Dim misValue As Object = System.Reflection.Missing.Value
xlApp = New Microsoft.Office.Interop.Excel.ApplicationClass
xlWorkBook = xlApp.Workbooks.Add(misValue)
' 打开某一个表单
xlWorkSheet = xlWorkBook.Sheets("sheet1")
' sql查询
' xlWorkBook.Sheets.Select("A1:A2")
Dim sql As String = "SELECT * FROM EMP"
' SqlAdapter
Dim dscmd As New SqlDataAdapter(sql, cnn.ConnectionString)
' 定义数据集
Dim ds As New DataSet
dscmd.Fill(ds)
‘添加字段信息到Excel表的第一行
xlWorkSheet.Cells(1, 1).Value = "First Name"
xlWorkSheet.Cells(1, 2).Value = "Last Name"
xlWorkSheet.Cells(1, 3).Value = "Full Name"
xlWorkSheet.Cells(1, 4).Value = "Salary"
' 将数据导入到excel
For i = 0 To ds.Tables(0).Rows.Count - 1
'Column
For j = 0 To ds.Tables(0).Columns.Count - 1
' this i change to header line cells
xlWorkSheet.Cells(i + 3, j + 1) = _
ds.Tables(0).Rows(i).Item(j)
Next
Next
'HardCode in Excel sheet
' this i change to footer line cells
xlWorkSheet.Cells(i + 3, 7) = "Total"
xlWorkSheet.Cells.Item(i + 3, 8) = "=SUM(H2:H18)"
' 保存到Excel
xlWorkSheet.SaveAs("D:\vbexcel.xlsx")
xlWorkBook.Close()
xlApp.Quit()
releaseObject(xlApp)
releaseObject(xlWorkBook)
releaseObject(xlWorkSheet)
'弹出对话框显示保存后的路径
MsgBox("You can find the file D:\vbexcel.xlsx")
Catch ex As Exception
End Try
End Sub
' Function of Realease Object in Excel Sheet
Private Sub releaseObject(ByVal obj As Object)
Try
System.Runtime.InteropServices.Marshal.ReleaseComObject(obj)
obj = Nothing
Catch ex As Exception
obj = Nothing
Finally
GC.Collect()
End Try
End Sub
End Class
复制代码。
第四步：
看到如下导出结果。